🧪 Active Ingredient Profile

Triclopyr Brush and Woody Weed Killer

Pyridine Herbicide (Synthetic Auxin)

Triclopyr is the go-to herbicide for killing woody plants, brush, stumps, and vines that 2,4-D cannot handle. It excels at killing poison ivy, wild blackberry, kudzu, woody brush, and tree stumps. Available in both amine (Garlon 3A) and ester (Garlon 4 Ultra) formulations.

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Classification
Pyridine Herbicide (Synthetic Auxin)
Signal Word
Caution to Danger (varies)
Mode of Action
Synthetic auxin: mimics growth hormone causing lethal uncontrolled growth in broadleaf and woody plants
Herbicide Auxin mechanism of action diagram

How herbicide auxin works โ€” illustrated mechanism of action

Target Pests

Woody brush, poison ivy and poison oak (excellent), wild blackberry, kudzu, multiflora rose, honeysuckle, buckthorn, privet, tree stumps (cut-stump treatment), woody vines. Also controls broadleaf weeds in lawns but 2,4-D is usually preferred for that purpose due to cost.

Products and Brand Names

Crossbow (Corteva - triclopyr + 2,4-D, the most popular brush killer), Garlon 3A (amine, professional), Garlon 4 Ultra (ester, professional), Ortho Brush-B-Gon, BioAdvanced Brush Killer Plus, Remedy Ultra (Corteva, rangeland). Cut-stump treatment formulations also available.

๐Ÿ“‹ Safety Data Sheet (SDS)

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Triclopyr Brush and Woody Weed Killer โ€” Safety Data Sheet

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๐Ÿ“„ Triclopyr Brush and Woody Weed Killer โ€” Safety Data Sheet ยท View the complete SDS document above or download below

Safety and Precautions

Moderate toxicity. Ester formulations are more irritating than amine. Wear long sleeves, gloves, and eye protection during mixing and application. Toxic to fish - do not apply near water bodies. Observe buffer zones.

Ester formulations and drift: Triclopyr ester (Garlon 4 Ultra) is highly volatile in hot weather. Do not apply when temperatures exceed 85F. Vapor drift can damage or kill trees, gardens, and ornamentals hundreds of feet from application site. Use amine formulations (Garlon 3A) in summer.

Pro Tips

For poison ivy: Triclopyr is the most effective herbicide for poison ivy. Apply Crossbow or Garlon to actively growing leaves in late spring/early summer. Full coverage of leaf surfaces is critical. Expect die-back within 2-4 weeks. Large established patches may need a second application.

Cut-stump treatment: For killing tree stumps and preventing regrowth, cut the tree and immediately (within 5 minutes) paint the cut surface with undiluted triclopyr ester (Garlon 4 Ultra). The herbicide travels down through the vascular system to kill the roots. Wait too long and the cut surface seals over.

For brush clearing: Crossbow (triclopyr + 2,4-D) applied as a foliar spray to actively growing brush is the standard professional approach. Use a pump sprayer or backpack sprayer with a flat fan nozzle for even coverage. Apply until leaves are wet but not dripping.

Selective in lawns: Triclopyr controls broadleaf weeds that 2,4-D misses, particularly ground ivy (creeping charlie) and wild violets. Some lawn herbicide products include triclopyr for this reason.

Did you know? Triclopyr was developed by Dow Chemical in the 1970s specifically to fill the gap that 2,4-D could not - woody plant control. The name Garlon comes from combining garland (wreath of plants) with on (against). It remains the most effective herbicide for woody invasive plant management in the US.
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Reviewed by Derek GiordanoContent reviewed by a licensed pest management professional. Last reviewed: April 2026.
๐Ÿ“š Sources: EPA Pesticide Labels ยท NPIC Pesticide Info
Published: Jan 1, 2025 ยท Updated: Apr 7, 2026